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The chemistry of the cyclopropyl group

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Published by Wiley in Chichester, New York .
Written in English

Subjects:

  • Cyclopropane.

Book details:

Edition Notes

Other titlesCyclopropyl group
Statementedited by Zvi Rappoport.
SeriesThe chemistry of functional groups
ContributionsRappoport, Zvi.
Classifications
LC ClassificationsQD305.H9 C48 1987
The Physical Object
Pagination :
ID Numbers
Open LibraryOL2381772M
ISBN 100471917389, 0471906581, 0471917370, 0471940747
LC Control Number87010440

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Parts 1 and 2of The Chemistry of the Cyclopropyl Group. Together they form a comprehensive review of the current state of research into cyclopropyl compounds. Literature coverage is provided up to mid in most chapters, with some areas of more recent coverage. Because of the interest in these compounds, the chapters cover all aspects of cyclopropyl compounds including structure, spectra Author: Zvi Rappoport. Rearrangements involving the cyclopropyl group / Jacques Salaun --Radiation chemistry and hot atom chemistry of cyclopropane and its derivatives / Zeev B. Alfassi --Electrochemistry of the cyclopropyl group / James Y. Becker --Biochemistry of the cyclopropyl group / Hung-Wen Liu and Christopher T. Walsh --Preparation and uses of isotopically. (source: Nielsen Book Data) This is the second part of "The Chemistry of the Cyclopropyl Group" and completes the coverage of Part 1. Together they form a comprehensive review of the current state of research into cyclopropyl compounds. Literature coverage is provided up to mid in most chapers, with some areas of more recent coverage. The Chemistry of the cyclopropyl group, Volume 1, Part 2 Volume 26 of Chemistry of functional groups The Chemistry of the Cyclopropyl Group, Zvi Rappoport, ISBN , Interscience publication: Editor: Zvi Rappoport: Publisher: Wiley, ISBN: , Length: pages: Subjects: Cyclopropane: Export.

Get this from a library! The Chemistry of the cyclopropyl group: volume 2. [Zvi Rappoport;]. Parts 1 and 2 of The Chemistry of the Cyclopropyl er they form a comprehensive review of the current state of research into cyclopropyl compounds. Literature coverage is provided up to mid in most chapters, with some areas of more recent coverage. Book Title:The Chemistry of the Cyclopropyl Group (Chemistry of Functional Groups) This is the second part of The Chemistry of the Cyclopropyl Group and completes the coverage of Part 1. Together they form a comprehensive review of the current state of research into cyclopropyl . Departments of Chemistry and Biology, Massachusetts Institute of Technology, Cambridge, MA , USA Book Series: PATAI'S Chemistry of Functional Groups. Series Editor(s): Cyclopropyl Group Formation via Addition of a One‐carbon Fragment from S‐Adenosylmethionine.

The chromophore of (11Z)-locked cyclopropyl retinal-7 (CPR ret7) consists of a cyclopropyl group flanked by polyene and enal moieties, and hence was expected to clarify the conjugative properties of the little known cyclopropyl group (CPR). As seen in Figs. A and B, the CD were of the exciton coupled bisignate type thus showing that the conjugative effect of CPR was minimal. aspects of radical chemistry. He has co-authored two books on radical chemistry. The cyclopropyl group exerts a small but significant stabiliz- ing effect on an adjacent radical centre. The cyclopropylmethyl C-H bond dissociation energy is kJ mol- l, which is slightly less than that of the C2H5-H bond dissociation energy ( kJ mol-. Recently, there has been an increasing use of the cyclopropyl ring in drug development to transition drug candidates from the preclinical to clinical stage. Important features of the cyclopropane ring are, the (1) coplanarity of the three carbon atoms, (2) relatively shorter ( Å) C–C bonds, (3) enhanced π-character of C–C bonds, and (4) C–H bonds are shorter and stronger than those.   A carbon with multiple substituents should have a lower number than a carbon with only one substituent or functional group. One way to make sure that the lowest number possible is assigned is to number the carbons so that when the numbers corresponding to the substituents are added, their sum is the lowest possible. 3-cyclopropyl